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N and V Coincorporated Ni Nanosheets for Enhanced Hydrogen Evolution Reaction
Tong, Rui1; Sun, Zhi2; Zhang, Fang1,3; Wang, Xina4; Xu, Jincheng1; Shi, Xingqiang3; Wang, Shuangpeng1; Pan, Hui1

Searching for earth-abundant and efficient electrocatalysts for large-scale hydrogen generation from the electrolysis of water is of paramount importance. Incorporating nonmetal or metal elements into host catalysts is a possible way to tune the catalytic capability of an electrocatalyst on the hydrogen evolution reaction (HER). Here, a simple and facile way was presented to synthesize N and V coincorporated Ni nanosheets on self-supported conductive carbon paper (NV-Ni/CP) as noble-metal-free catalysts for the HER Compared with Ni/CP, the NV-Ni/CP shows better HER property with low overpotential of 95 mV (10 mA cm(-2)), small Tafel slope (140 mV dec(-1)), and superior long-term stability. We further show that the outstanding HER performance of NV-Ni/CP is ascribed to the increased active sites and enhanced conductivity. It is expected that the coincorporation of nonmetal and metal elements will provide more chances to enhance the HER catalytic ability and extend the scope of cost-effective electrocatalysts.

KeywordNv-ni/cp Nanosheets Coincorporation Her
URLView the original
Indexed BySCIE
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Engineering
WOS SubjectChemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS IDWOS:000452344900065
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Cited Times [WOS]:22   [WOS Record]     [Related Records in WOS]
Document TypeJournal article
CollectionUniversity of Macau
Corresponding AuthorWang, Shuangpeng; Pan, Hui
Affiliation1.Univ Macau, Inst Appl Phys & Mat Engn, Minist Educ, Joint Key Lab, Macau, Peoples R China;
2.Xidian Univ, Sch Microelect, State Key Discipline Lab Wide Bandgap Semicond Te, Xian 710071, Shaanxi, Peoples R China;
3.Southern Univ Sci & Technol, Dept Phys, Shenzhen 518055, Guangdong, Peoples R China;
4.Hubei Univ, Fac Phys & Elect Sci, Hubei Key Lab Ferro & Piezoelect Mat & Devices, Wuhan 430062, Hubei, Peoples R China
First Author AffilicationUniversity of Macau
Corresponding Author AffilicationUniversity of Macau
Recommended Citation
GB/T 7714
Tong, Rui,Sun, Zhi,Zhang, Fang,et al. N and V Coincorporated Ni Nanosheets for Enhanced Hydrogen Evolution Reaction[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(12):16525-16531.
APA Tong, Rui,Sun, Zhi,Zhang, Fang,Wang, Xina,Xu, Jincheng,Shi, Xingqiang,Wang, Shuangpeng,&Pan, Hui.(2018).N and V Coincorporated Ni Nanosheets for Enhanced Hydrogen Evolution Reaction.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(12),16525-16531.
MLA Tong, Rui,et al."N and V Coincorporated Ni Nanosheets for Enhanced Hydrogen Evolution Reaction".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.12(2018):16525-16531.
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